Kinetic Monte Carlo study of triplet-triplet annihilation in organic phosphorescent emitters
نویسندگان
چکیده
منابع مشابه
Triplet - Triplet Annihilation Upconversion in Solid Materials
Upconversion is the observation of high energy photon emission from low energy photon absorption. 1 Among the multiple upconversion mechanisms, one that has drawn recent interest is triplet-triplet annihilation (TTA). TTA holds significant advantages over its upconversion counterparts including its use of simple, tunable molecules and its ability to operate under low intensity, non-coherent lig...
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The sun is the only renewable energy source that can accommodate humanity’s energy needs today and in the foreseeable future. The sunlight reaching the planet’s surface is filtrated through the atmosphere, reducing its UV-light intensity in the 300-400 nm range, which indeed can be harmful to life as we know it in too large doses. However, many useful photoreactions require in practice such hig...
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Understanding the temperature dependency of triplet-triplet annihilation upconversion (TTA-UC) is important for optimizing biological applications of upconversion. Here the temperature dependency of red-to-blue TTA-UC is reported in a variety of neutral PEGylated phospholipid liposomes. In these systems a delicate balance between lateral diffusion rate of the dyes, annihilator aggregation, and ...
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We hereby present a simple method for reducing the effect of oxygen quenching in Triplet-Triplet Annihilation Upconversion (TTA-UC) systems. A number of commercially available thioethers and one thiol have been tested as singlet oxygen scavengers. Recording of the upconverted emission from a well-studied PdOEP (sensitizer)-DPA (annihilator/emitter) couple has been made over time with steady-sta...
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In light harvesting complex II (LHCII) of higher plants and green algae, carotenoids (Cars) have an important function to quench chlorophyll (Chl) triplet states and therefore avoid the production of harmful singlet oxygen. The resulting Car triplet states lead to a non-linear self-quenching mechanism called singlet-triplet (S-T) annihilation that strongly depends on the excitation density. In ...
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ژورنال
عنوان ژورنال: Journal of Applied Physics
سال: 2015
ISSN: 0021-8979,1089-7550
DOI: 10.1063/1.4914460